Microwave‐Assisted Pyrolysis‐A New Way for the Sustainable Recycling and Upgrading of Plastic and Biomass: A Review

The efficient utilization of organic solid waste resources can help reducing the consumption of conventional fossil fuels, mitigating environmental pollution, and achieving green sustainable development. Due to its dual nature of being both a resource and a source of pollution, it is crucial to implement suitable recycling technologies throughout the recycling and upgrading processes for plastics and biomass, which are organic solid wastes with complex mixture of components. The conventional pyrolysis and hydropyrolysis were summarized for recycling plastics and biomass into high‐value fuels, chemicals, and materials. To enhance reaction efficiency and improve product selectivity, microwave‐assisted pyrolysis was introduced to the upgrading of plastics and biomass through efficient energy supply especially with the aid of catalysts and microwave absorbers. This review provides a detail summary of microwave‐assisted pyrolysis for plastics and biomass from the technical, applied, and mechanistic perspectives. Based on the recent technological advances, the future directions for the development of microwave‐assisted pyrolysis technologies are predicted. Break through the dilemma of traditional thermos‐chemicals pathways and face the challenge of directional cleavage of the C−C bonds under mild conditions, the review provides a detail summary of microwave‐assisted pyrolysis for plastics and biomass from the technical, applied, and mechanistic perspectives along with the future predication.