Boiling water resistant fully bio-based adhesive made from maleated chitosan and glucose with excellent performance

Biomass resources are widely considered potential alternatives to formaldehyde-based wood adhesives because of their abundance. In this study, an environmentally friendly biomass adhesive, carboxylated chitosan-glucose (CSC-G), was prepared using chitosan, maleic anhydride, and glucose. The structure and water resistance of the adhesive were analyzed in detail. Maleic anhydride act as a bridge connecting chitosan and glucose, giving the adhesive good water solubility and resistance. The improved water resistance of the CSC-G adhesive was attributed to the formation of covalent cross-linked structures and an increased degree of system cross-linking. Additionally, the curing temperature of the CSC-G adhesive was superior to those of previously reported polyester adhesives. This study not only expands the application scope of fishery waste, but also demonstrates its great potential for the preparation of high-performance plywood. [Display omitted] •A strategy of molecular chain extension was adopted to prepare the bio-based adhesive CSC-G.•The ester cross-linking structure endowed the adhesive with high shear strength and water resistance.•A feasible solution for the wide application of chitosan in wood adhesive was justified.