Field induced slow magnetic relaxation in a linear homotrinuclear manganese heterospin coordination compound with S = 7/2 ground state and intriguing spin density distribution

Field induced slow magnetic relaxation in a linear homotrinuclear manganese heterospin coordination compound with S = 7/2 ground state and intriguing spin density distribution

We report a first example of field-induced ( = 2500 Oe) slow magnetization relaxation in the homotrinuclear linear heterospin manganese coordination compound with = 7/2 ground state, based on the bidentate 3,5-di- -butyl-1,2-benzoquinone-1-monooxime (HL) ligand with composition {[MnL ]Mn[MnL ]}.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2024-04, Vol.53 (16), p.6860-6864
Hauptverfasser: Shcherbakov, Igor N, Krotkii, Ilya I, Kazachkova, Victoria I, Lyubchenko, Sergey N, Efimov, Nikolay N, Tsaturyan, Arshak A, Lazarenko, Vladimir A
Format: Artikel
Sprache:eng
Schlagworte:
Benzoquinone
Coordination compounds
Density distribution
Ground state
Magnetic induction
Magnetic relaxation
Manganese
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Zusammenfassung:We report a first example of field-induced ( = 2500 Oe) slow magnetization relaxation in the homotrinuclear linear heterospin manganese coordination compound with = 7/2 ground state, based on the bidentate 3,5-di- -butyl-1,2-benzoquinone-1-monooxime (HL) ligand with composition {[MnL ]Mn[MnL ]}.
ISSN:1477-9226
1477-9234
DOI:10.1039/d3dt04123a