Catalytic System-Controlled Regioselective 1,2- and 1,4-Carboannulations of [60]Fullerene

Catalytic System-Controlled Regioselective 1,2- and 1,4-Carboannulations of [60]Fullerene

Selective functionalization of fullerenes is an important but challenging topic in fullerene chemistry and synthetic chemistry. Here we present the first example of catalytic system-controlled regioselective 1,2- and 1,4-addition reactions for the flexible and efficient synthesis of novel 1,2- and 1...

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Veröffentlicht in:Organic letters 2024-04, Vol.26 (13), p.2552-2557
Hauptverfasser: Liu, Tong-Xin, Ru, Yifei, Guo, Wenyue, Ma, Nana, Yang, Panting, Li, Xiaojun, Zhang, Pengling, Bi, Jingjing, Zhang, Guisheng
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Sprache:eng
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Zusammenfassung:Selective functionalization of fullerenes is an important but challenging topic in fullerene chemistry and synthetic chemistry. Here we present the first example of catalytic system-controlled regioselective 1,2- and 1,4-addition reactions for the flexible and efficient synthesis of novel 1,2- and 1,4-carbocycle-fused fullerenes via a palladium-catalyzed decarboxylative carboannulation process.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.4c00482