Direct S0 → Tn Transition under Visible Light Irradiation Enabling Synthesis of a Pseudoindoxyl Scaffold

Direct S0 → Tn Transition under Visible Light Irradiation Enabling Synthesis of a Pseudoindoxyl Scaffold

Pseudoindoxyl is a partial skeleton found in various natural products. Its light-absorption properties make it useful for the design of functional molecules. However, versatile synthesis methods have not yet been reported. In this report, we present a versatile synthetic method for pseudoindoxyls us...

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Veröffentlicht in:Organic letters 2024-04, Vol.26 (15), p.3289-3293
Hauptverfasser: Nakajima, Masaya, Nagasawa, Sho, Yamazaki, Keita, Yazawa, Tomohiro, Yoneyama, Honoka, Kotaka, Yuko, Nemoto, Tetsuhiro
Format: Artikel
Sprache:eng
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Zusammenfassung:Pseudoindoxyl is a partial skeleton found in various natural products. Its light-absorption properties make it useful for the design of functional molecules. However, versatile synthesis methods have not yet been reported. In this report, we present a versatile synthetic method for pseudoindoxyls using the direct S0 → Tn transition under visible light irradiation. We also discuss the application of pseudoindoxyls as photocatalysts.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.4c00957