Photocatalytic redox-neutral α-C(sp 3 )-H pyridination of glycine derivatives and N -arylamines with cyanopyridines

A photo-induced α-C(sp )-H decyanative pyridination of -arylglycine derivatives with cyanopyridines was developed. This reaction was performed under organic photocatalytic and redox-neutral conditions a radical-radical cross-coupling process. Besides, the protocol was also suitable for the C(sp )-H...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-04, Vol.60 (33), p.4451-4454
Hauptverfasser: Pan, Changduo, Chen, Dongdong, Cheng, Yangjian, Yu, Jin-Tao
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Chen, Dongdong
Cheng, Yangjian
Yu, Jin-Tao
description A photo-induced α-C(sp )-H decyanative pyridination of -arylglycine derivatives with cyanopyridines was developed. This reaction was performed under organic photocatalytic and redox-neutral conditions a radical-radical cross-coupling process. Besides, the protocol was also suitable for the C(sp )-H pyridination of -aryl tetrahydroisoquinolines as well as benzylamines.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Amines
Cross coupling
Glycine
Organic compounds
title Photocatalytic redox-neutral α-C(sp 3 )-H pyridination of glycine derivatives and N -arylamines with cyanopyridines
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