Photocatalytic redox-neutral α-C(sp 3 )-H pyridination of glycine derivatives and N -arylamines with cyanopyridines

Photocatalytic redox-neutral α-C(sp 3 )-H pyridination of glycine derivatives and N -arylamines with cyanopyridines

A photo-induced α-C(sp )-H decyanative pyridination of -arylglycine derivatives with cyanopyridines was developed. This reaction was performed under organic photocatalytic and redox-neutral conditions a radical-radical cross-coupling process. Besides, the protocol was also suitable for the C(sp )-H...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-04, Vol.60 (33), p.4451-4454
Hauptverfasser: Pan, Changduo, Chen, Dongdong, Cheng, Yangjian, Yu, Jin-Tao
Format: Artikel
Sprache:eng
Schlagworte:
Amines
Cross coupling
Glycine
Organic compounds
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Zusammenfassung:A photo-induced α-C(sp )-H decyanative pyridination of -arylglycine derivatives with cyanopyridines was developed. This reaction was performed under organic photocatalytic and redox-neutral conditions a radical-radical cross-coupling process. Besides, the protocol was also suitable for the C(sp )-H pyridination of -aryl tetrahydroisoquinolines as well as benzylamines.
ISSN:1359-7345
1364-548X
DOI:10.1039/d4cc00906a