Study of Ru barrier failure in the Cu/Ru/Si system

The reaction mechanisms and related microstructures in the Cu/Si, Ru/Si, and Cu/Ru/Si metallization system were studied experimentally. With the help of sheet resistance measurements, x-ray diffraction, field-emission scanning electron microscopy, secondary ion mass spectroscopy, and transmission el...

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Veröffentlicht in:Journal of materials research 2007-09, Vol.22 (9), p.2505-2511
Hauptverfasser: Damayanti, M., Sritharan, T., Mhaisalkar, S.G., Phoon, E., Chan, L.
Format: Artikel
Sprache:eng
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Zusammenfassung:The reaction mechanisms and related microstructures in the Cu/Si, Ru/Si, and Cu/Ru/Si metallization system were studied experimentally. With the help of sheet resistance measurements, x-ray diffraction, field-emission scanning electron microscopy, secondary ion mass spectroscopy, and transmission electron microscopy, the metallization structure with Ru barrier layer was observed to fail completely at temperatures around 700 °C, regardless of the Ru thickness because of the formation of polycrystalline Ru2Si3 followed by Cu3Si protrusions.
ISSN:0884-2914
2044-5326
DOI:10.1557/jmr.2007.0310