A Combined Top-Down/Bottom-Up Approach for the Nanoscale Patterning of Spin-Crossover Coordination Polymers

A Combined Top-Down/Bottom-Up Approach for the Nanoscale Patterning of Spin-Crossover Coordination Polymers

Micro‐ and nanometer‐sized patterns of the spin‐crossover compound Fe(pyrazine)[Pt(CN)4] have been fabricated using a combination of lift‐off and multilayer sequential assembly methods. These patterns (see figure and inside cover) exhibit a bistability of their electronic states and, thus, represent...

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Veröffentlicht in:Advanced materials (Weinheim) 2007-08, Vol.19 (16), p.2163-2167
Hauptverfasser: Molnár, G., Cobo, S., Real, J. A., Carcenac, F., Daran, E., Vieu, C., Bousseksou, A.
Format: Artikel
Sprache:eng
Schlagworte:
bistable
coordination
Iron complexes
Layer-by-layer assembly
Multilayers
Nanostructures
Nanostructures, bistable
Polymers
Polymers, coordination
Spin crossover
Surface patterning
Thin films
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Beschreibung
Zusammenfassung:Micro‐ and nanometer‐sized patterns of the spin‐crossover compound Fe(pyrazine)[Pt(CN)4] have been fabricated using a combination of lift‐off and multilayer sequential assembly methods. These patterns (see figure and inside cover) exhibit a bistability of their electronic states and, thus, represent a novel platform for a wide array of potential applications.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200700448