Preparation and properties of Sb-doped SnO2/metal substrates by sol-gel and dip coating

Antimony-doped SnO2 on a metallic substrate is a useful electrode for electrochemical water treatment. Sb-doped SnO2 films on aluminium and stainless steel were prepared by the sol-gel technique and dip coating method. The precursor metal alkoxide/alcohol solutions were derived from SnCl4 and SbCl3....

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Veröffentlicht in:Ceramics international 2007-05, Vol.33 (4), p.625-629
Hauptverfasser: SEO, M, AKUTSU, Y, KAGEMOTO, H
Format: Artikel
Sprache:eng
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Zusammenfassung:Antimony-doped SnO2 on a metallic substrate is a useful electrode for electrochemical water treatment. Sb-doped SnO2 films on aluminium and stainless steel were prepared by the sol-gel technique and dip coating method. The precursor metal alkoxide/alcohol solutions were derived from SnCl4 and SbCl3. Ammonia/alcohol solution was used for the synthesis and Cl- was eliminated by the precipitation of NH4Cl. The XRD pattern of the SnO2 film annealed at 400 C could be assigned to SnO2. The Sb-SnO2 film consisted of fine particles from 10 to 20 nm. In the electrolysis, Sb-SnO2/stainless steel electrodes showed an exfoliation but Sb-SnO2/aluminium did not. The results indicated that SnO2/Al can be promising as a SnO2 electrode for electrochemical water treatment. 21 refs.
ISSN:0272-8842
1873-3956
DOI:10.1016/j.ceramint.2005.11.013