Morphological evolution and characterization of hydrothermal synthesized Na2CuP2O7 crystals

Na2CuP2O7 crystals were synthesized by hydrothermal technique at moderate pressure-temperature conditions. The maximum degree of crystallinity is observed at critical concentration of initial components, beyond which the crystallinity collapses sharply to minimum. Solubility studies have revealed, p...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2007-04, Vol.452-453, p.751-757
Hauptverfasser:	MAHESH, M. J, GOPALAKRISHNA, G. S, ASHAMANJARI, K. G
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: electronic structure, electrical, magnetic, and optical properties Cross-disciplinary physics: materials science rheology Diamagnetism, paramagnetism and superparamagnetism Exact sciences and technology Growth from solutions Magnetic properties and materials Materials science Methods of crystal growth physics of crystal growth Nonmetals Physics
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Na2CuP2O7 crystals were synthesized by hydrothermal technique at moderate pressure-temperature conditions. The maximum degree of crystallinity is observed at critical concentration of initial components, beyond which the crystallinity collapses sharply to minimum. Solubility studies have revealed, positive thermal coefficient of solubility in a H3PO4 solvent with relatively high enthalpy. Thermal behaviour and structural coordination of the prepared materials were investigated, respectively, using DTA/TGA and FTIR measurements. Magnetic results have revealed; it is a frequency and temperature dependent prospective paramagnetic material.
ISSN:	0921-5093 1873-4936
DOI:	10.1016/j.msea.2006.10.135