Physical and structural properties of glasses in the TeO2-TiO2-Nb2O5 system

Twelve glasses in the TeO2-TiO2-Nb2O5 system were prepared. The glass forming region in the TeO2-TiO2-Nb2O5 ternary system was determined. The structural role of each component was studied by FTIR and some physical properties (density, molar volume, oxygen molar volume, transition temperature, thermal expansion coefficient, optical absorption and energy gap) were determined. The glass structure is mainly built by [TeO4] groups, while Nb5+ and Ti4+ ions act as network modifiers. As the Nb2O5 and TiO2 concentration increased, [TeO4] groups progressively changed to [TeO3] groups as a consequence of the network opening. The contribution of the three ions to the oxygen molar volume followed the order: Te4+ > Ti4+ > Nb5+. TiO2 incorporation and even more Nb2O5 improve the glass thermal stability and the network reinforcement. TiO2 contributed the most to decrease the glass energy gap. 33 refs.