From potassium alkalide and benzyl glycidyl ether to crown-like macroinitiator with alkoxide active centres

From potassium alkalide and benzyl glycidyl ether to crown-like macroinitiator with alkoxide active centres

Cyclic oligoether with alkoxide groups is obtained in the reaction of alkalide K −, K +(15-crown-5) 2 with benzyl glycidyl ether. This oligoether contains potassium glycidoxide units and benzyl glycidyl ether units. Its use as a macroinitiator should lead to star-shaped polymers with a cyclic core....

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Veröffentlicht in:Reactive & functional polymers 2007-02, Vol.67 (2), p.120-126
Hauptverfasser: Stolarzewicz, Andrzej, Morejko, Barbara, Grobelny, Zbigniew, Trzebicka, Barbara, Sułkowski, Wiesław W.
Format: Artikel
Sprache:eng
Schlagworte:
Alkalide
Applied sciences
Benzyl glycidyl ether
Exact sciences and technology
Macroinitiator
Organic polymers
Physicochemistry of polymers
Polymerization
Potassium glycidoxide
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Zusammenfassung:Cyclic oligoether with alkoxide groups is obtained in the reaction of alkalide K −, K +(15-crown-5) 2 with benzyl glycidyl ether. This oligoether contains potassium glycidoxide units and benzyl glycidyl ether units. Its use as a macroinitiator should lead to star-shaped polymers with a cyclic core.
ISSN:1381-5148
DOI:10.1016/j.reactfunctpolym.2006.10.003