Enhancing copper and lead adsorption in water by in-situ generation of calcium carbonate on alginate/chitosan biocomposite surfaces

Chitosan (CS) and sodium alginate (SA)-based biocomposites (CSA) were prepared with the in-situ generation of Calcium Carbonate (CSAX_Ca) through a simple, straightforward, economical, and eco-friendly procedure. Different drying conditions (X) were tested to achieve suitable structural and surface characteristics to enhance adsorption capacity: freeze-dried (L), vacuum-dried with methanol (M), and freeze-dried + vacuum-dried with methanol (LM). Temperature and adsorbent dosage effects on the adsorption capacity of Cu2+ or Pb2+ were examined. Results showed that the higher-yielding biocomposite (CSALM_Ca) exhibited rapid adsorption and good diffusion properties, achieving removal above 90 % within contaminant initial concentration ranges of 10–100 mg/L. At 35 °C, a pseudo-second-order kinetic and the Langmuir model effectively described kinetics and isotherms, revealing maximum adsorption (qe, max) of 429 mgCu2+/L and 1742 mgPb2+/g. Characterization through FTIR, XRD, and SEM of the as-prepared adsorbents confirmed the presence of CaCO3 in vaterite and calcite forms and the influence of drying conditions on the material morphology. Post-adsorption material characterization, in combination with adsorption findings, revealed chemisorption processes involving Ca2+ ion exchange for Cu2+ or Pb2+, resulting in surface-insoluble compounds. The best-performing material showed that after three reuse cycles, the removal of Cu2+ and Pb2+ decreased to 75 % and 62 %, respectively. •Eco-friendly chitosan/alginate/CaCO3 adsorbents for Cu and Pb water remotion.•Vacuum drying with methanol led to calcite formation, hindering heavy metal removal.•Freeze-drying and methanol-water replacement increased vaterite and calcite generation.•In-situ CaCO3 generation on chitosan/alginate composites for Cu and Pb high removal•CaCO3 enhances copper and lead adsorption in chitosan/alginate bio-composites.•Remarkable removal capacity of chitosan/alginate/calcium carbonate bio-adsorbents.•Drying methods impact material structure; lyophilization improves diffusion.