Processing of porous TiN/C ceramics from biological templates

A novel synthesis process, based on a sol infiltration and carbothermal reduction–nitridation of titania, has been developed for producing porous TiN/C ceramics from biological templates. During processing at 1400 °C under higher nitrogen pressure the biocarbon reacted with TiO 2 and N 2. The morpho...

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Veröffentlicht in:Materials letters 2007, Vol.61 (1), p.186-188
Hauptverfasser: Luo, Min, Gao, Jiqiang, Zhang, Xiao, Yang, Jianfeng, Hou, Guangya, Ouyang, Da, Jin, Zhihao
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Sprache:eng
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Zusammenfassung:A novel synthesis process, based on a sol infiltration and carbothermal reduction–nitridation of titania, has been developed for producing porous TiN/C ceramics from biological templates. During processing at 1400 °C under higher nitrogen pressure the biocarbon reacted with TiO 2 and N 2. The morphology and phase structure of the resulting materials were characterized by scanning electron microscopy and X-Ray diffraction, respectively. The results show that the resulting TiN/C ceramics contained residual carbon, which remains covered by cubic phase TiN. The conversion process retains the microcellular morphology of the original pinewood tissue.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2006.04.027