Ultralarge and Thermally Stable Electro-optic Activities from Diels-Alder Crosslinkable Polymers Containing Binary Chromophore Systems

Ultralarge and Thermally Stable Electro-optic Activities from Diels-Alder Crosslinkable Polymers Containing Binary Chromophore Systems

The dispersion of an efficient secondary chromophore into in situ crosslinked nonlinear optical polymer networks is described. The secondary chromophore leads to both enhanced electro‐optical (EO) activity (> 260 pm V–1 at 1.31 μm) and alignment stability at 85 °C. Analysis of the EO properties s...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Weinheim) 2006-11, Vol.18 (22), p.3038-3042
Hauptverfasser: Kim, T.-D., Luo, J., Ka, J.-W., Hau, S., Tian, Y., Shi, Z., Tucker, N. M., Jang, S.-H., Kang, J.-W., Jen, A. K.-Y.
Format: Artikel
Sprache:eng
Schlagworte:
Chromophores
Electro-optical materials
Photonic materials
Poly(methyl methacrylate)
Polymers
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The dispersion of an efficient secondary chromophore into in situ crosslinked nonlinear optical polymer networks is described. The secondary chromophore leads to both enhanced electro‐optical (EO) activity (> 260 pm V–1 at 1.31 μm) and alignment stability at 85 °C. Analysis of the EO properties shows exceptional poling efficiency of these binary systems at high chromophore loading levels, in contrast to experimental results obtained from single‐chromophore polymers.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200601582