Flow injection determination of p-aminophenol at trace level using inhibited luminol–dimethylsulfoxide–NaOH–EDTA chemiluminescence

A novel flow injection procedure was developed for the determination of p-aminophenol (PAP) based on the inhibition by PAP of the chemiluminescence from luminol–dimethylsulfoxide (DMSO)–NaOH–EDTA system. The method has merits of higher sensitivity, wider linear range, simpler procedure, and a more rapid analyzing speed. It is applicable for the determination of PAP in the range of 2.5×10 −10–5.0×10 −8 g mL −1 with a detection limit of 1.9×10 −10 g mL −1. The relative standard deviation (RSD) for 5.0×10 −9 g mL −1 PAP is 0.78% ( n=15). The method has been successfully used to determine PAP in industrial wastewaters and environmental waters. Additionally, the inhibition mechanism was also discussed briefly.