Sintering of tin oxide using zinc oxide as a densification aid

The physicochemical electronic characteristics of SnO2 render it useful in many technical applications, including ceramic varistors, stable electrodes used in electric glass-melting furnaces and electrometallurgy of aluminum, transparent windows and chemical sensors. The use of ZnO as a sintering ai...

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Veröffentlicht in:Journal of materials science 2004-09, Vol.39 (18), p.5825-5830
Hauptverfasser: FOSCHINI, C. R, PERAZOLLI, L, VARELA, J. A
Format: Artikel
Sprache:eng
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Zusammenfassung:The physicochemical electronic characteristics of SnO2 render it useful in many technical applications, including ceramic varistors, stable electrodes used in electric glass-melting furnaces and electrometallurgy of aluminum, transparent windows and chemical sensors. The use of ZnO as a sintering aid was explored in this study to obtain SnO2 as a dense ceramic. Compacts were obtained by mechanical mixing of oxides, isostatic pressing at 210 MPa and sintering in situ inside a dilatometer at heating rates of 10 deg C/min. The grain size and microstructure were investigated by scanning and transmission electron microscopy (SEM/TEM). The phases and chemical composition were analyzed by energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD). The results indicated that ZnO acts as a densification aid for SnO2, improving its grain growth with additions of up to 2 mol%. ZnO forms a solid solution with SnO2 up to 1 mol%, above which SnZn03 precipitates in the grain boundary, potentially inhibiting shrinkage and grain growth.
ISSN:0022-2461
1573-4803
DOI:10.1023/b:jmsc.0000040095.03906.61