Advances in Hierarchical Inorganic Nanostructures for Efficient Solar Energy Harvesting Systems

The urgent need to address the global energy and environmental crisis necessitates the development of efficient solar‐power harvesting systems. Among the promising candidates, hierarchical inorganic nanostructures stand out due to their exceptional attributes, including a high specific surface area, abundant active sites, and tunable optoelectronic properties. In this comprehensive review, we delve into the fundamental principles underlying various solar energy harvesting technologies, including dye‐sensitized solar cells (DSSCs), photocatalytic, photoelectrocatalytic (water splitting), and photothermal (water purification) systems, providing a foundational understanding of their operation. Thereafter, the discussion is focused on recent advancements in the synthesis, design, and development of hierarchical nanostructures composed of diverse inorganic material combinations, tailored for each of these solar energy harvesting systems. We meticulously elaborate on the distinct synthesis methods and conditions employed to fine‐tune the morphological features of these hierarchical nanostructures. Furthermore, this review offers profound insights into critical aspects such as electron transfer mechanisms, band gap engineering, the creation of hetero‐hybrid structures to optimize interface chemistry through diverse synthesis approaches, and precise adjustments of structural features. Beyond elucidating the scientific fundamentals, this review explores the large‐scale applications of the aforementioned solar harvesting systems. Additionally, it addresses the existing challenges and outlines the prospects for achieving heightened solar‐energy conversion efficiency. Efforts to combat the global energy crisis are driving the development of efficient solar‐power harvesting devices. This review investigates the fundamental principles and efficiency of solar energy harvesting systems designed using hierarchical inorganic nanostructures, which are synthesized rationally through various methods. Insights into electron transfer mechanisms and interface chemistry are discussed, alongside challenges and prospects for improved solar‐energy conversion efficiency.