The effect of gamma radiation on the stability of miniature reference electrodes

The design and fabrication of four types of miniature reference electrodes and their long term stability in a radiation field are described. Miniature versions of a saturated calomel electrode (MSCE), a silver/silver chloride electrode (MAG), a tungsten/tungsten oxide (MWO) and a copper/copper ion (...

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Veröffentlicht in:Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2006-09, Vol.75 (9), p.927-931
Hauptverfasser: Galuszka-Muga, B., Muga, M.L., Hanrahan, R.J.
Format: Artikel
Sprache:eng
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Zusammenfassung:The design and fabrication of four types of miniature reference electrodes and their long term stability in a radiation field are described. Miniature versions of a saturated calomel electrode (MSCE), a silver/silver chloride electrode (MAG), a tungsten/tungsten oxide (MWO) and a copper/copper ion (MCU) electrode were tested in a 10 kGy/h (1 Mrad/h) radiation field for up to 30 days total at 25 and 40 °C. The latter two (MWO and MCU) varied appreciably over time periods of several hours whereas the former two (MSCE and MAG) varied less than 1 mV over periods of 6–8 h and are deemed suitable as reference electrodes for corrosion studies of systems immersed in a radiation field at elevated temperature.
ISSN:0969-806X
1879-0895
DOI:10.1016/j.radphyschem.2006.02.006