A twofold interpenetrated two-dimensional zinc(II) coordination polymer for the highly sensitive detection of nitrofurantoin in aqueous medium
A novel Zn coordination polymer, namely, poly[{μ -bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone-κ N :N }(μ -5-bromobenzene-1,3-dicarboxylato-κ O :O )zinc(II)], [Zn(C H BrO )(C H N O)] or [Zn(Br-BDC)(MIPMO)] , (I), has been synthesized by the solvothermal method using 5-bromoisophthalic acid (Br-...
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Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2024-04, Vol.80 (4), p.98-103 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A novel Zn
coordination polymer, namely, poly[{μ
-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone-κ
N
:N
}(μ
-5-bromobenzene-1,3-dicarboxylato-κ
O
:O
)zinc(II)], [Zn(C
H
BrO
)(C
H
N
O)]
or [Zn(Br-BDC)(MIPMO)]
, (I), has been synthesized by the solvothermal method using 5-bromoisophthalic acid (Br-H
BDC), bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]methanone (MIPMO) and Zn(NO
)
·6H
O. Structure analysis showed that compound (I) displays twofold parallel interwoven sql nets. Fluorescence experiments confirmed that the compound can sensitively and selectively detect nitrofurantoin (NFT) in aqueous medium. In addition, the possible fluorescence quenching mechanisms of compound (I) toward NFT are investigated. |
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ISSN: | 2053-2296 0108-2701 2053-2296 1600-5759 |
DOI: | 10.1107/S2053229624002171 |