Synthesis and chelation properties of Mannich polymers derived from piperazine and some hydroxy benzaldoximes

Two new oxime containing polymers, poly(salicylaldoxime-3,5-diyl (piperazine N, N′-bismethylene)), polymer I, and poly(2,4-dihydroxy-benzaldoxime-3,5-diyl (piperazine N, N′-bismethylene)), polymer II, were prepared through Mannich-type condensation of the appropriate hydroxy benzaldoxime with formaldehyde and piperazine. The sorption properties of these polymers towards the trivalent lanthanide ions, Gd 3+, Tb 3+, Sm 3+, Nd 3+, and La 3+ were studied by a batch equilibration technique as a function of contact time, pH, and counter ion. Polymer II exhibited improved chelation characteristics in comparison with polymer I and displayed faster rates of metal ion uptake and relatively higher capacities and selectivities.