Preparation of tannic acid-reinforced cellulose nanofiber composites for all-water-based high-performance wood adhesives
Traditional adhesives easily release toxic gases during the preparation process or apply to wood composite products, which have adverse effects on the human body and the environment. Herein, an all-water-based high-performance wood adhesive is prepared using TEMPO-oxidized cellulose nanofiber (TOCNF...
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Veröffentlicht in: | International journal of biological macromolecules 2024-04, Vol.264 (Pt 2), p.130770-130770, Article 130770 |
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Sprache: | eng |
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Zusammenfassung: | Traditional adhesives easily release toxic gases during the preparation process or apply to wood composite products, which have adverse effects on the human body and the environment. Herein, an all-water-based high-performance wood adhesive is prepared using TEMPO-oxidized cellulose nanofiber (TOCNF), acrylamide (AM), and tannic acid (TA) through free radical polymerization. Different characteristics of the prepared composites, including morphology, injectability, and adhesion properties, have been investigated. Results showed that the TA/TOCNF/PAM composite has excellent injectability. The addition of TA can enhance the lap shear strength of the TA/TOCNF/PAM composites and with the increment of TA content, the lap shear strength gradually decreases. The formation of effective hydrogen bonds and Van der Waals interaction among the rich functional groups in the composite, lead to strong lap shear strength on different substrates. The composite with 5.0 g of AM, 5.0 g of the TOCNF suspension and 0.1 g TA possesses a high lap shear strength of 10.5 MPa on wood and 1.5 MPa on aluminium. Based on strong adhesion properties and excellent injectability, the TA/TOCNF/PAM composites have great potential in the furniture construction and building industries.
An all-water-based high-performance wood adhesive was fabricated through free radical polymerization. [Display omitted]
•An all-water-based high-performance wood adhesive was fabricated through free radical polymerization.•TA/TOCNF/PAM composite has the strongest lap shear strength for wood substrates.•TA/TOCNF/PAM composite has excellent injectability. |
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ISSN: | 0141-8130 1879-0003 |
DOI: | 10.1016/j.ijbiomac.2024.130770 |