Utilisation of carbon dioxide and nitrate for urea electrosynthesis with a Cu-based metal-organic framework
It is important and challenging to utilise CO 2 and NO 3 − as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO 4 active sites, as an efficient electrocatalyst for coupling CO 2 and NO 3 − into urea, achieving a hi...
Gespeichert in:
Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-03, Vol.6 (27), p.3669-3672 |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | It is important and challenging to utilise CO
2
and NO
3
−
as a feedstock for electrosynthesis of urea. Herein, we reported a stable 2D metal-organic framework (MOF) Cu-HATNA, possessing planar CuO
4
active sites, as an efficient electrocatalyst for coupling CO
2
and NO
3
−
into urea, achieving a high yield rate of 1.46 g h
−1
g
cat
−1
with a current density of 44.2 mA cm
−1
at −0.6 V
vs.
RHE. This performance surpasses most of the previously reported catalysts, revealing the great prospects of MOFs in sustainable urea synthesis.
A hexagonal 2D Cu-based MOF with planar CuO
4
nodes, denoted as
Cu-HATNA
, was developed and employed as an electrocatalyst for direct electrosynthesis of urea from CO
2
and NO
3
−
. |
---|---|
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d3cc05821b |