Preparation and characterisation of carbon-coated ceramic foams for organic vapour adsorption

Ceramic foam substrates of various porosities were coated with novolak resin, which was then subsequently carbonised and activated to develop a pore structure. The carbon forming the layer was characterised by thermal analysis, TPD and N 2, CO 2 and hexane vapour adsorption. It was found to be micro...

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Veröffentlicht in:Carbon (New York) 2006-06, Vol.44 (7), p.1189-1197
Hauptverfasser: Dawson, E.A., Barnes, P.A., Chinn, M.J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Ceramic foam substrates of various porosities were coated with novolak resin, which was then subsequently carbonised and activated to develop a pore structure. The carbon forming the layer was characterised by thermal analysis, TPD and N 2, CO 2 and hexane vapour adsorption. It was found to be microporous with a high surface area (up to 1400 m 2 g −1), which made it a good adsorbent for hexane vapour at ambient temperature. The carbon–ceramic interface was examined using SEM. The coated foams displayed a reduced pressure drop compared to carbon granules and had good dynamic hexane vapour adsorption characteristics. Depending on the foam architecture, hexane breakthrough was delayed for up to 78 min.
ISSN:0008-6223
1873-3891
DOI:10.1016/j.carbon.2005.10.053