A Microscopic Theory of Current Density Spikes Associated with Phase Transitions on Crystalline Electrodes
A microscopic theory that can be used to generate voltammogram spikes associated with first-order phase transitions is presented. The theory can be readily applied to experimental voltammogram spikes in order to determine microscopic properties of the phases involved in the associated transitions.
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| Veröffentlicht in: | International journal of thermophysics 2006-11, Vol.27 (6), p.1882-1889 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A microscopic theory that can be used to generate voltammogram spikes associated with first-order phase transitions is presented. The theory can be readily applied to experimental voltammogram spikes in order to determine microscopic properties of the phases involved in the associated transitions. |
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| ISSN: | 0195-928X 1572-9567 |
| DOI: | 10.1007/s10765-006-0117-3 |