Comparison of the evaporation processes of classical spectrography and optical spectrometry tandem technique for the determination of the relevant environmental elements

The evaporation as a part of the spectrochemical excitation process is a complicated procedure during which different thermo-chemical reactions connected mainly to the formation of carbides are overshot. This one is accelerated namely at the 4000K on the top of the carrier electrode. The carbide cre...

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Veröffentlicht in:Mikrochimica acta (1966) 2006-11, Vol.156 (1-2), p.115-120
Hauptverfasser: Ružičková, Silvia, Bajuszová, Jolana, Koller, Ladislav, Matherny, Mikuláš, Flórián, Karol
Format: Artikel
Sprache:eng
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Zusammenfassung:The evaporation as a part of the spectrochemical excitation process is a complicated procedure during which different thermo-chemical reactions connected mainly to the formation of carbides are overshot. This one is accelerated namely at the 4000K on the top of the carrier electrode. The carbide creation markedly affects the evaporation process of single elements of the given matrix and modifies this process. In spite of this it is evident that the intensity of the DC arc has a significant impact on the evaporation of all elements.
ISSN:0026-3672
1436-5073
DOI:10.1007/s00604-006-0604-z