A polyaniline supported PtRu nanocomposite anode and a Pd-impregnated nanocomposite Nafion membrane for DMFCs
Nanocomposites of PtRu nanoparticles and polyaniline (an electronically conducting polymer) were synthesized by the borohydride reduction method in an aqueous solution for the anode electrode in direct methanol fuel cells (DMFCs). Due to the high electronic conductivity of polyaniline, the methanol...
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Veröffentlicht in: | Solid state ionics 2005-12, Vol.176 (39), p.3031-3034 |
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container_title | Solid state ionics |
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creator | Choi, Jong-Ho Kim, Young-Min Lee, Jae-Suk Cho, Ki-Yun Jung, Ho-Young Park, Jung-Ki Park, In-Su Sung, Yung-Eun |
description | Nanocomposites of PtRu nanoparticles and polyaniline (an electronically conducting polymer) were synthesized by the borohydride reduction method in an aqueous solution for the anode electrode in direct methanol fuel cells (DMFCs). Due to the high electronic conductivity of polyaniline, the methanol oxidation current for polyaniline supported PtRu nanocomposites was similar to that of carbon supported PtRu catalysts. In addition, Pd-impregnated nanocomposite Nafion membranes were suggested to enhance DMFC performance by blocking or reducing methanol crossover and their characteristics were affected by the impregnation time of Pd-nanoparticles. |
doi_str_mv | 10.1016/j.ssi.2005.09.041 |
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Due to the high electronic conductivity of polyaniline, the methanol oxidation current for polyaniline supported PtRu nanocomposites was similar to that of carbon supported PtRu catalysts. 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Due to the high electronic conductivity of polyaniline, the methanol oxidation current for polyaniline supported PtRu nanocomposites was similar to that of carbon supported PtRu catalysts. In addition, Pd-impregnated nanocomposite Nafion membranes were suggested to enhance DMFC performance by blocking or reducing methanol crossover and their characteristics were affected by the impregnation time of Pd-nanoparticles.</description><subject>Direct methanol fuel cell</subject><subject>Nafion</subject><subject>Pd nanocomposites</subject><subject>Polyaniline</subject><issn>0167-2738</issn><issn>1872-7689</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-AG85eWtNmzRJ8bSsrgr-WUTPIU2nkqVtatIK--1NWS9evLxh4PceMw-hy4ykGcn49S4NwaY5IUVKypSw7AgtMinyRHBZHqNFZESSCypP0VkIO0IIp5IvULfCg2v3uret7QGHaRicH6HG2_Ftwr3unXHd4IIdAcelnrXGGm_rxHaDh89ez_Rf8EU31vW4g67yOqY2zuPb5806nKOTRrcBLn7nEn1s7t7XD8nT6_3jevWUGJrLMakrLowu8xyaEiQQyvKGS8E45dToTLMqiuAV5YWgTBSUEUYKXjHeyAKqii7R1SF38O5rgjCqzgYDbRuvcVNQecnKshAigtkBNN6F4KFRg7ed9nuVETUXq3YqFqvmYhUpVSw2em4OHogffFvwKhgLvYHaejCjqp39x_0DHeKB5Q</recordid><startdate>20051201</startdate><enddate>20051201</enddate><creator>Choi, Jong-Ho</creator><creator>Kim, Young-Min</creator><creator>Lee, Jae-Suk</creator><creator>Cho, Ki-Yun</creator><creator>Jung, Ho-Young</creator><creator>Park, Jung-Ki</creator><creator>Park, In-Su</creator><creator>Sung, Yung-Eun</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20051201</creationdate><title>A polyaniline supported PtRu nanocomposite anode and a Pd-impregnated nanocomposite Nafion membrane for DMFCs</title><author>Choi, Jong-Ho ; Kim, Young-Min ; Lee, Jae-Suk ; Cho, Ki-Yun ; Jung, Ho-Young ; Park, Jung-Ki ; Park, In-Su ; Sung, Yung-Eun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-db67ca922ef9e8e0342f68746363ca1a4ba1a76b365734753404056b46f85ebb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Direct methanol fuel cell</topic><topic>Nafion</topic><topic>Pd nanocomposites</topic><topic>Polyaniline</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Choi, Jong-Ho</creatorcontrib><creatorcontrib>Kim, Young-Min</creatorcontrib><creatorcontrib>Lee, Jae-Suk</creatorcontrib><creatorcontrib>Cho, Ki-Yun</creatorcontrib><creatorcontrib>Jung, Ho-Young</creatorcontrib><creatorcontrib>Park, Jung-Ki</creatorcontrib><creatorcontrib>Park, In-Su</creatorcontrib><creatorcontrib>Sung, Yung-Eun</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Choi, Jong-Ho</au><au>Kim, Young-Min</au><au>Lee, Jae-Suk</au><au>Cho, Ki-Yun</au><au>Jung, Ho-Young</au><au>Park, Jung-Ki</au><au>Park, In-Su</au><au>Sung, Yung-Eun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A polyaniline supported PtRu nanocomposite anode and a Pd-impregnated nanocomposite Nafion membrane for DMFCs</atitle><jtitle>Solid state ionics</jtitle><date>2005-12-01</date><risdate>2005</risdate><volume>176</volume><issue>39</issue><spage>3031</spage><epage>3034</epage><pages>3031-3034</pages><issn>0167-2738</issn><eissn>1872-7689</eissn><abstract>Nanocomposites of PtRu nanoparticles and polyaniline (an electronically conducting polymer) were synthesized by the borohydride reduction method in an aqueous solution for the anode electrode in direct methanol fuel cells (DMFCs). Due to the high electronic conductivity of polyaniline, the methanol oxidation current for polyaniline supported PtRu nanocomposites was similar to that of carbon supported PtRu catalysts. In addition, Pd-impregnated nanocomposite Nafion membranes were suggested to enhance DMFC performance by blocking or reducing methanol crossover and their characteristics were affected by the impregnation time of Pd-nanoparticles.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.ssi.2005.09.041</doi><tpages>4</tpages></addata></record> |
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source | Elsevier ScienceDirect Journals |
subjects | Direct methanol fuel cell Nafion Pd nanocomposites Polyaniline |
title | A polyaniline supported PtRu nanocomposite anode and a Pd-impregnated nanocomposite Nafion membrane for DMFCs |
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