A polyaniline supported PtRu nanocomposite anode and a Pd-impregnated nanocomposite Nafion membrane for DMFCs

Nanocomposites of PtRu nanoparticles and polyaniline (an electronically conducting polymer) were synthesized by the borohydride reduction method in an aqueous solution for the anode electrode in direct methanol fuel cells (DMFCs). Due to the high electronic conductivity of polyaniline, the methanol...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Solid state ionics 2005-12, Vol.176 (39), p.3031-3034
Hauptverfasser: Choi, Jong-Ho, Kim, Young-Min, Lee, Jae-Suk, Cho, Ki-Yun, Jung, Ho-Young, Park, Jung-Ki, Park, In-Su, Sung, Yung-Eun
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Nanocomposites of PtRu nanoparticles and polyaniline (an electronically conducting polymer) were synthesized by the borohydride reduction method in an aqueous solution for the anode electrode in direct methanol fuel cells (DMFCs). Due to the high electronic conductivity of polyaniline, the methanol oxidation current for polyaniline supported PtRu nanocomposites was similar to that of carbon supported PtRu catalysts. In addition, Pd-impregnated nanocomposite Nafion membranes were suggested to enhance DMFC performance by blocking or reducing methanol crossover and their characteristics were affected by the impregnation time of Pd-nanoparticles.
ISSN:0167-2738
1872-7689
DOI:10.1016/j.ssi.2005.09.041