On the incorporation mechanism of Fe in GaN grown by metal-organic vapour phase epitaxy

We report an investigation of the incorporation mechanism of iron (Fe) as a dopant in GaN grown by MOVPE. A series of Fe doped GaN structures were studied by secondary ion mass spectrometry (SIMS), atomic force microscopy (AFM) and X‐ray photo‐electron spectroscopy (XPS). A model is presented which...

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Veröffentlicht in:Physica status solidi. C 2006-06, Vol.3 (6), p.1429-1434
Hauptverfasser: Balmer, R. S., Soley, D. E. J., Simons, A. J., Mace, J. D., Koker, L., Jackson, P. O., Wallis, D. J., Uren, M. J., Martin, T.
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container_end_page 1434
container_issue 6
container_start_page 1429
container_title Physica status solidi. C
container_volume 3
creator Balmer, R. S.
Soley, D. E. J.
Simons, A. J.
Mace, J. D.
Koker, L.
Jackson, P. O.
Wallis, D. J.
Uren, M. J.
Martin, T.
description We report an investigation of the incorporation mechanism of iron (Fe) as a dopant in GaN grown by MOVPE. A series of Fe doped GaN structures were studied by secondary ion mass spectrometry (SIMS), atomic force microscopy (AFM) and X‐ray photo‐electron spectroscopy (XPS). A model is presented which describes the SIMS concentration profiles with excellent agreement, and, it is shown that Fe incorporation into GaN occurs via a surface segregation mechanism. This model is supported by direct measurement of a highly Fe‐rich layer on the surface of Fe doped GaN by XPS. Furthermore, we find that the presence of Fe on the GaN surface promotes a transition from 2D to 3D GaN growth which is confirmed by AFM measurements of RMS roughness with increasing Fe flux. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
doi_str_mv 10.1002/pssc.200565282
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subjects 64.75.+g
66.30.Jt
68.55.Ln
81.15.Gh
82.80.Ms
82.80.Pv
title On the incorporation mechanism of Fe in GaN grown by metal-organic vapour phase epitaxy
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