Polysiloxane–Cellulose acetate butyrate cellulose interpenetrating polymers networks close to true IPNs on a large composition range. Part II

Interpenetrating polymer networks combining cellulose acetate butyrate (CAB) and α,ω-divinyl-polydimethylsiloxane (PDMS) in different weight proportions have been synthesized. The synthesis involves a one pot–one shot process in which all components are first mixed together. For each composition, th...

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Veröffentlicht in:Polymer (Guilford) 2006-05, Vol.47 (11), p.3747-3753
Hauptverfasser: Vidal, Frédéric, Fichet, Odile, Laskar, Judith, Teyssié, Dominique
Format: Artikel
Sprache:eng
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Zusammenfassung:Interpenetrating polymer networks combining cellulose acetate butyrate (CAB) and α,ω-divinyl-polydimethylsiloxane (PDMS) in different weight proportions have been synthesized. The synthesis involves a one pot–one shot process in which all components are first mixed together. For each composition, the relative CAB and PDMS network formation rates are adjusted through the concentration of DBTDL used as CAB network formation catalyst. Thus, the chemically independent networks are formed quasi-simultaneously in order to avoid phase separation. The CAB cross-linking density effect on the PDMS/CAB IPN mechanical properties has also been particularly studied. All synthesized IPNs are transparent and only one mechanical relaxation temperature lying between those of the single CAB and PDMS networks is observed by DMTA analysis. These results show that the networks are correctly interpenetrated and no phase separation is observed at the DMTA level. Some mechanical properties of the PDMS network are significantly improved in this IPN combination and their stress–strain behavior has highlighted a synergistic effect arising from the IPN architecture. Thus, these IPNs exhibit many characteristics, which would allow defining them as close to ‘true’ IPNs.
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2006.03.030