Generation of Carbonyl Compounds from Oximes through Electrooxidative Deoximation
An electrochemical protocol was developed to generate carbonyl compounds from oximes with excellent functional group compatibility. Mechanistic experimental studies support the idea that an electrooxidative pathway of oximes might be involved, in which the water may serve as an oxygen nucleophile an...
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| Veröffentlicht in: | Journal of organic chemistry 2024-03, Vol.89 (6), p.4199-4204 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | An electrochemical protocol was developed to generate carbonyl compounds from oximes with excellent functional group compatibility. Mechanistic experimental studies support the idea that an electrooxidative pathway of oximes might be involved, in which the water may serve as an oxygen nucleophile and the oxygen source for the final carbonyl compounds. |
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| ISSN: | 0022-3263 1520-6904 |
| DOI: | 10.1021/acs.joc.3c02631 |