Cobalt(II)-Copper(II) Bimetallic Chains as a New Class of Single-Chain Magnets

Cobalt(II)-Copper(II) Bimetallic Chains as a New Class of Single-Chain Magnets

An oxamato‐bridged CoIICuII chain compound has been obtained via the self‐assembly of mononuclear bis‐bidentate copper(II) anionic building blocks and cobalt(II) cations. It is the first example of a heterobimetallic ferrimagnetic chain that incorporates slow magnetic relaxation behavior (see Figure...

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Veröffentlicht in:Advanced materials (Weinheim) 2004-09, Vol.16 (18), p.1597-1600
Hauptverfasser: Pardo, E., Ruiz-García, R., Lloret, F., Faus, J., Julve, M., Journaux, Y., Delgado, F., Ruiz-Pérez, C.
Format: Artikel
Sprache:eng
Schlagworte:
Magnetic properties
Single chain magnets (SCMs)
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Zusammenfassung:An oxamato‐bridged CoIICuII chain compound has been obtained via the self‐assembly of mononuclear bis‐bidentate copper(II) anionic building blocks and cobalt(II) cations. It is the first example of a heterobimetallic ferrimagnetic chain that incorporates slow magnetic relaxation behavior (see Figure).
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200400253