Robust Solid-State Na-CO2 Battery with Na2.7Zr2Si2PO11.7F0.3-PVDF-HFP Composite Solid Electrolyte and Na15Sn4/Na Anode

Solid-state Na-CO2 batteries are a kind of energy storage devices that can immobilize and convert CO2. They have the advantages of both solid-state batteries and metal–air batteries. High-performance solid electrolyte and electrode materials are important for improving the performance of solid-state Na-CO2 batteries. In this work, we investigate the influence of fluorine doping on the structure and ionic conductivity of Na3Zr2Si2PO12 (NZSP). An ionic conductive solid electrolyte membrane was prepared by compositing the inorganic solid electrolyte Na2.7Zr2Si2PO11.7F0.3 (NZSPF3) with poly­(vinylidene fluoride)-co-hexafluoropropylene (PVDF-HFP). It shows an ionic conductivity of up to 2.17 × 10–4 S cm–1 at room temperature, a high sodium ionic transfer number of ∼0.70, a broad electrochemical window of ∼5.18 V, and better mechanical strength. Furthermore, we studied the Na15Sn4/Na composite foil with the ability to inhibit dendrite as the anode for solid-state Na-CO2 batteries. Through density functional theory (DFT) calculations, the Na15Sn4 particle has been verified with a strong sodiophilic property, which reduces the nucleation barrier during the deposition process, leading to a lower overpotential. The symmetric cell assembled with the composite solid-state electrolyte NZSPF3-PVDF-HFP and Na15Sn4/Na composite anode can inhibit the growth of Na dendrites effectively and maintain the stability of the whole cell structure. Solid-state Na-CO2 batteries assembled with Ru-carbon nanotube (Ru-CNTs) as cathode catalysts exhibit a high discharge capacity of 6371.8 mAh g–1 at 200 mA g–1, excellent cycling stability for 1100 h, and good rate performance. This work provides a promising strategy for designing high-performance solid-state Na-CO2 batteries.