Luminescence of oxygen related defects in zirconia nanocrystals

The luminescence of undoped tetragonal structure ZrO2 nanocrystals was studied. The luminescence intensity depends on oxygen content in gases mixture in which the nanocrystals were annealed. The distorted Zr‐O bond is suggested to be the recombination center for band carriers. The oxygen deficient d...

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Veröffentlicht in:Physica status solidi. C 2007-03, Vol.4 (3), p.770-773
Hauptverfasser: Smits, K., Grigorjeva, L., Łojkowski, W., Fidelus, J. D.
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Sprache:eng
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Zusammenfassung:The luminescence of undoped tetragonal structure ZrO2 nanocrystals was studied. The luminescence intensity depends on oxygen content in gases mixture in which the nanocrystals were annealed. The distorted Zr‐O bond is suggested to be the recombination center for band carriers. The oxygen deficient defect is proposed to be responsible for photoluminescence. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
ISSN:1862-6351
1610-1634
1610-1642
DOI:10.1002/pssc.200673850