Microstructural study and size control of iron oxide nanoparticles produced by microemulsion technique

In this paper we study the possibility to control the size of iron oxide (Fe3O4) nanoparticles by the microemulsion technique. We used a water‐in‐oil reverse microemulsion system with n‐hexadecil trimethylammonium bromide (CTAB) as a cationic surfactant, n‐butanol as a co‐surfactant, n‐hexanol as a continuous oil phase, and aqueous phase. The magnetite nanopowders were synthesized by a single microemulsion technique in which the aqueous phase contains only metal ions (Fe2+ and Fe3+). The particle size of the powders varied in the range of 14–36 nm depending on the preparation conditions. We studied the influence of changing the water/surfactant ratio (W 0 = 5, 10, 15, 20) and the metallic ion (Fe2+ and Fe3+) concentration on the particle size distribution and crystallinity of Fe3O4. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)