Immobilization of Pb in waste water and soil by tourmaline-biochar composites (TBs): Characteristics and mechanisms

Novel tourmaline-biochar composites (TBs) were synthesized by introducing tourmaline (TM) into pomelo peel biochar (BC). The surface properties of TBs and BC were studied and the adsorption performances for Pb2+ were investigated. Compared to pristine BC, the adsorption ability for Pb2+ on TBs was enhanced with the increase of TM in TBs, and up to 514.62 mg/g on 5%TB. The enrichment of inorganic metals caused by TM in TBs made the precipitation and cation ion exchange become the main mechanisms in adsorbing Pb2+, and the amounts of adsorbing Pb2+ by those two mechanisms on TBs were 1.10–1.48 times and 1.20–1.30 times those of BC, respectively. Furthermore, applying TBs to practical contaminated soil increased the soil pH and electrical conductivity (EC) after 15 days of incubation. The increased content of residual-Pb and reduced exchangeable-Pb and DTPA-Pb indicated that TBs were favorable for the immobilization of Pb in soil. This study gives a new perspective on the synthesis of tourmaline-biochar composite and their application in Pb-polluted water and soil. [Display omitted] •Novel tourmaline-biochar composites (TBs) were synthesized for Pb2+ adsorption.•TBs show higher adsorption ability for Pb2+ than BC, Qm reaches 432.05–514.62 mg/g.•Enhanced adsorption of Pb2+ on TBs relies on the improvement of Qci and Qpre.•The application of TBs in soil decreased the content of exchangeable-Pb.