High‐Performance Flexible Broadband Photoelectrochemical Photodetector Based on Molybdenum Telluride

Flexible broadband photodetectors are desired but challenging to be fabricated for next‐generation wearable intelligent optoelectronic devices. Considering the narrow bandgap and strong light absorption, molybdenum telluride (MoTe2) based photoelectrochemical photodetectors are successfully assembled by liquid phase exfoliation accompanied with the electrophoretic deposited method. This MoTe2‐based photodetector shows a broadband detection in ultraviolet–near‐infrared band, long‐term stability within 18000 s, and fast response in millisecond‐level (response time≈19 ms, recovery time≈26 ms). More importantly, even though the MoTe2 photodetector is bent and twisted at a high degree for several hundred times, it still shows excellent flexibility with stable on‐off switching characteristics. Additionally, this photodetector displays a good response for rotation angles in the range from 0° to 360°, and the extracted Iph maintain almost the same value approximately 0.97 µA cm−2, suggesting an omnidirectional detection capability. This work demonstrates the proposed flexible photoanode shows a great potential in future broadband omnidirectional detection systems. The molybdenum telluride (MoTe2) based photoelectrochemical photodetector is fabricated by liquid phase exfoliation accompanied by the electrophoretic deposited method. This MoTe2‐based photodetector shows a broadband detection in ultraviolet–near‐infrared band, long‐term stability within 18 000 s, and fast response in millisecond‐level. More importantly, this photodetector shows excellent flexibility and folding resistance, as well as omnidirectional detection capability.