Upcycling of Agricultural Waste Stream to High‐Molecular‐Weight Bio‐based Poly(ethylene 2,5‐furanoate)

Orange peel and sugar beet pulp contain large quantities of pectin, which can be turned via galactaric acid into furan dicarboxylic acid (FDCA) and its esters. In this work, we show the polymerisation of these FDCA esters into high‐molecular‐weight, 70–100 kg/mol, poly(ethylene 2,5‐furanoate) (PEF). PEF is an emerging bio‐based alternative for poly(ethylene terephthalate) (PET), widely used in for example packaging applications. Closing the loop, we also demonstrated and confirmed that PEF can be hydrolysed by enzymes, which are known to hydrolyse PET, back into FDCA for convenient recycling and recovery of monomers. Orange peel and sugar beet pulp contain pectin, which can be turned into furan dicarboxylic acid (FDCA) and its esters. In this work, we show the polymerisation of these esters into high‐molecular‐weight poly(ethylene 2,5‐furanoate) (PEF). PEF is an emerging bio‐based alternative for poly(ethylene terephthalate) (PET). Closing the loop, we also demonstrated and confirmed that PEF can be hydrolysed by enzymes.