Planar three-coordinate iron(II) complexes supported by sterically demanding -Si(SiMe 3 ) 2 (SiMe 2 t Bu) ligands

Planar three-coordinate iron(II) complexes supported by sterically demanding -Si(SiMe 3 ) 2 (SiMe 2 t Bu) ligands

Sterically demanding organosilyl ligands support the formation of coordinatively unsaturated complexes. In this study, we found that using the ligand -Si(SiMe ) (SiMe Bu) affords exclusively planar three-coordinate iron bis(silyl) complexes that show good catalytic performance in the hydrosilylation...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2024-01, Vol.53 (4), p.1421-1424
Hauptverfasser: Ishii, Reon, Sunada, Yusuke
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Sprache:eng
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Acetophenone
Hydrosilylation
Iron
Ligands
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Ishii, Reon
Sunada, Yusuke
description Sterically demanding organosilyl ligands support the formation of coordinatively unsaturated complexes. In this study, we found that using the ligand -Si(SiMe ) (SiMe Bu) affords exclusively planar three-coordinate iron bis(silyl) complexes that show good catalytic performance in the hydrosilylation of acetophenone.
doi_str_mv 10.1039/d3dt04130a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Acetophenone
Hydrosilylation
Iron
Ligands
title Planar three-coordinate iron(II) complexes supported by sterically demanding -Si(SiMe 3 ) 2 (SiMe 2 t Bu) ligands
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