Planar three-coordinate iron(II) complexes supported by sterically demanding -Si(SiMe 3 ) 2 (SiMe 2 t Bu) ligands
Sterically demanding organosilyl ligands support the formation of coordinatively unsaturated complexes. In this study, we found that using the ligand -Si(SiMe ) (SiMe Bu) affords exclusively planar three-coordinate iron bis(silyl) complexes that show good catalytic performance in the hydrosilylation...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-01, Vol.53 (4), p.1421-1424 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Sterically demanding organosilyl ligands support the formation of coordinatively unsaturated complexes. In this study, we found that using the ligand -Si(SiMe
)
(SiMe
Bu) affords exclusively planar three-coordinate iron bis(silyl) complexes that show good catalytic performance in the hydrosilylation of acetophenone. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/d3dt04130a |