Building Stable Anodes for High‐Rate Na‐Metal Batteries

Due to low cost and high energy density, sodium metal batteries (SMBs) have attracted growing interest, with great potential to power future electric vehicles (EVs) and mobile electronics, which require rapid charge/discharge capability. However, the development of high‐rate SMBs has been impeded by the sluggish Na+ ion kinetics, particularly at the sodium metal anode (SMA). The high‐rate operation severely threatens the SMA stability, due to the unstable solid‐electrolyte interface (SEI), the Na dendrite growth, and large volume changes during Na plating‐stripping cycles, leading to rapid electrochemical performance degradations. This review surveys key challenges faced by high‐rate SMAs, and highlights representative stabilization strategies, including the general modification of SMB components (including the host, Na metal surface, electrolyte, separator, and cathode), and emerging solutions with the development of solid‐state SMBs and liquid metal anodes; the working principle, performance, and application of these strategies are elaborated, to reduce the Na nucleation energy barriers and promote Na+ ion transfer kinetics for stable high‐rate Na metal anodes. This review will inspire further efforts to stabilize SMAs and other metal (e.g., Li, K, Mg, Zn) anodes, promoting high‐rate applications of high‐energy metal batteries towards a more sustainable society. This review highlights the fundamental challenges associated with sodium metal anodes (SMAs) for high‐rate sodium metal batteries, and it systematically discusses general modifications of Na battery components and emerging strategies to stabilize SMAs. Finally, the review ends with the perspective on future development of high‐rate sodium metal batteries.