High rate performance of highly dispersed C60 on activated carbon capacitor

Fullerene-activated carbon composite electrodes were prepared and their charge/discharge characteristics were studied for use in a high power electric double-layer capacitor. The capacitance of the C60-loaded activated carbon fiber (ACF) electrodes became greater than that of the unloaded ACF at cha...

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Veröffentlicht in:Electrochimica acta 2005-11, Vol.51 (5), p.972-977
Hauptverfasser: OKAJIMA, Keiichi, IKEDA, Atsushi, KAMOSHITA, Kazunori, SUDOH, Masao
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Sprache:eng
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Zusammenfassung:Fullerene-activated carbon composite electrodes were prepared and their charge/discharge characteristics were studied for use in a high power electric double-layer capacitor. The capacitance of the C60-loaded activated carbon fiber (ACF) electrodes became greater than that of the unloaded ACF at charge/discharge current densities above 50 mA/cm2. In order to obtain a highly dispersed C60-loaded electrode, an ultrasonic treatment was performed. The size of the C60 agglomerate decreased from 1-2 to 0.1 mm or less, and the capacitance of the C60loaded ACF electrodes increased with an increase in the ultrasonic treatment time. A higher capacitance of 172 F/g was obtained at 50 mA/cm2 on a 1 wt% C60-loaded electrode with ultrasonic treatment, and the C60-loaded ACF electrode also showed a higher cycle performance.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2005.04.055