Growth and concentration dependencies of rare-earth doped lithium niobate single crystals

A series of lithium niobate LiNbO 3 (LN) single crystals doped by rare-earth elements (Tm, Er, Dy, Tb, Gd, Pr) were grown under the same conditions by the Czochralski technique in a wide range of dopant concentrations. The distribution coefficients of rare-earth elements in the “crystal—melt” system...

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Veröffentlicht in:Journal of crystal growth 2006-06, Vol.291 (2), p.390-397
Hauptverfasser: Palatnikov, M.N., Biryukova, I.V., Sidorov, N.V., Denisov, A.V., Kalinnikov, V.T., Smith, P.G.R., Shur, V.Ya
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container_end_page 397
container_issue 2
container_start_page 390
container_title Journal of crystal growth
container_volume 291
creator Palatnikov, M.N.
Biryukova, I.V.
Sidorov, N.V.
Denisov, A.V.
Kalinnikov, V.T.
Smith, P.G.R.
Shur, V.Ya
description A series of lithium niobate LiNbO 3 (LN) single crystals doped by rare-earth elements (Tm, Er, Dy, Tb, Gd, Pr) were grown under the same conditions by the Czochralski technique in a wide range of dopant concentrations. The distribution coefficients of rare-earth elements in the “crystal—melt” system of LN were determined at the beginning of the crystal growth. Their dependence on the dopant concentration in melt ranging from 0.1 to 3.5 wt% was investigated. Concentration dependences of physicochemical, ferroelectric and structural characteristics of doped LN single crystals were studied using X-ray diffraction, thermal analysis and Raman scattering measurements. A mechanism of rare-earth elements incorporation into the crystal lattice of LN was proposed for a wide range of dopant concentrations.
doi_str_mv 10.1016/j.jcrysgro.2006.03.022
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subjects A1. Crystal structure
A1. Doping
A1. Point defects
A2. Single crystals growth
B1. Niobates
B2. Ferroelectric materials
title Growth and concentration dependencies of rare-earth doped lithium niobate single crystals
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