Trifunctional L‐Cysteine Assisted Construction of MoO2/MoS2/C Nanoarchitecture Toward High‐Rate Sodium Storage

The volume collapse and slow kinetics reaction of anode materials are two key issues for sodium ion batteries (SIBs). Herein, an “embryo” strategy is proposed for synthesis of nanorod–embedded MoO2/MoS2/C network nanoarchitecture as anode for SIBs with high‐rate performance. Interestingly, L‐cysteine which plays triple roles including sulfur source, reductant, and carbon source can be utilized to produce the sulfur vacancy–enriched heterostructure. Specifically, L‐cysteine can combine with metastable monoclinic MoO3 nanorods at room temperature to encapsulate the “nutrient” of MoOx analogues (MoO2.5(OH)0.5 and MoO3·0.5H2O) and hydrogen‐deficient L‐cysteine in the “embryo” precursor affording for subsequent in situ multistep heating treatment. The resultant MoO2/MoS2/C presents a high‐rate capability of 875 and 420 mAh g−1 at 0.5 and 10 A g−1, respectively, which are much better than the MoS2‐based anode materials reported by far. Finite element simulation and analysis results verify that the volume expansion can be reduced to 42.8% from 88.8% when building nanorod–embedded porous network structure. Theoretical calculations reveal that the sulfur vacancies and heterointerface engineering can promote the adsorption and migration of Na+ leading to highly enhanced thermodynamic and kinetic reaction. The work provides an efficient approach to develop advanced electrode materials for energy storage. Assisted by metastable MoO3 nanorods and trifunctional L‐cysteine, an “embryo” strategy that involves the pre‐encapsulation of “nutrient” and in situ multistep heating treatment is proposed to produce MoO2/MoS2/C nanoarchitecture. Benefiting from nanorod–embedded network configuration and sulfur vacancy–enriched heterostructure, the volume expansion and slow kinetics are highly improved. The MoO2/MoS2/C presented much higher rate capacity than the MoS2‐based anodes reported by far.