Crystal, Solution, and Computational Study of the Structure of Ortho‐Lithium N,N‐Diisopropyl‐P,P‐Diphenylphosphinothioic Amide

The first crystal structure of an ortho‐lithium phosphinothioic amide complexed with tetramethylethylenediamine 12 is reported. The complex consists of a spirane in which the spiro‐lithium is N,N‐ and C,S‐chelated by the diamine and organophosphorus ligands, respectively. The analogous ortho anion 1...

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Veröffentlicht in:	Chemistry : a European journal 2024-03, Vol.30 (17), p.e202303785-n/a
Hauptverfasser:	Belmonte‐Sánchez, Eva, García‐López, Jesús, Navarro, Yolanda, Iglesias, María José, Fernández, Ignacio, López‐Ortiz, Fernando
Format:	Artikel
Sprache:	eng
Schlagworte:	anionic dearomatization Anions CIPE mechanism Crystal structure Density functional theory Diamines directed metalation Lithium Magnetic studies NMR Nuclear magnetic resonance ortho-lithiation phosphinothioic amide Room temperature Spiro compounds
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