Organo‐Photoredox Catalyzed C(sp3)−H Bond Arylation of Aliphatic Amides
A C(sp3)−H bond arylation of aliphatic amides has been achieved via organophotoredox catalysis. The reaction could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and a range of aliphatic amides is employed as bo...
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| Veröffentlicht in: | ChemSusChem 2024-04, Vol.17 (8), p.e202301585-n/a |
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| creator | Yi, Yaping Xi, Chanjuan |
| description | A C(sp3)−H bond arylation of aliphatic amides has been achieved via organophotoredox catalysis. The reaction could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and a range of aliphatic amides is employed as both substrate and solvent in the reaction. This photocatalyzed transformation provides a convenient protocol to afford a board range of N‐benzyl amides.
A C(sp3)−H bond arylation of aliphatic amides with cyanoaromatics has been achieved via photoredox catalysis, which could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and aliphatic amide is employed as both reagent and solvent. This photocatalyzed transformation provides a convenient protocol to afford a board range of N‐benzyl amides. |
| doi_str_mv | 10.1002/cssc.202301585 |
| format | Article |
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A C(sp3)−H bond arylation of aliphatic amides with cyanoaromatics has been achieved via photoredox catalysis, which could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and aliphatic amide is employed as both reagent and solvent. This photocatalyzed transformation provides a convenient protocol to afford a board range of N‐benzyl amides.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.202301585</identifier><identifier>PMID: 38126961</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>aliphatic amide ; Aliphatic compounds ; Amides ; Catalysis ; cyanoaromatic compound ; C−H bond activation ; C−H bond arylation ; Hydrogen bonds ; Light sources ; photocatalysis ; Photoredox catalysis ; Reagents ; Room temperature ; Substrates</subject><ispartof>ChemSusChem, 2024-04, Vol.17 (8), p.e202301585-n/a</ispartof><rights>2023 Wiley-VCH GmbH</rights><rights>2023 Wiley-VCH GmbH.</rights><rights>2024 Wiley-VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3285-aa5a62f122694666e34117ece8de9544d353860d6a050dfd70b8cdfcfff4c7433</cites><orcidid>0000-0002-9602-7309</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.202301585$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.202301585$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38126961$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yi, Yaping</creatorcontrib><creatorcontrib>Xi, Chanjuan</creatorcontrib><title>Organo‐Photoredox Catalyzed C(sp3)−H Bond Arylation of Aliphatic Amides</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>A C(sp3)−H bond arylation of aliphatic amides has been achieved via organophotoredox catalysis. The reaction could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and a range of aliphatic amides is employed as both substrate and solvent in the reaction. This photocatalyzed transformation provides a convenient protocol to afford a board range of N‐benzyl amides.
A C(sp3)−H bond arylation of aliphatic amides with cyanoaromatics has been achieved via photoredox catalysis, which could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and aliphatic amide is employed as both reagent and solvent. This photocatalyzed transformation provides a convenient protocol to afford a board range of N‐benzyl amides.</description><subject>aliphatic amide</subject><subject>Aliphatic compounds</subject><subject>Amides</subject><subject>Catalysis</subject><subject>cyanoaromatic compound</subject><subject>C−H bond activation</subject><subject>C−H bond arylation</subject><subject>Hydrogen bonds</subject><subject>Light sources</subject><subject>photocatalysis</subject><subject>Photoredox catalysis</subject><subject>Reagents</subject><subject>Room temperature</subject><subject>Substrates</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKw0AUhgdRrFa3LiXgpi5az2QuSZY1eMOCggruhnEuNpJm6kyKxpVLl-Ij-iSmVCu4cXXOge_8_HwI7WAYYID4QIWgBjHEBDBL2QrawCmnfcbp7epyJ7iDNkN4AOCQcb6OOiTFMc843kDnF_5eVu7z9f1y7GrnjXbPUS5rWTYvRkd5L0zJ_ufbx2l06CodDX1TyrpwVeRsNCyL6bi9VDScFNqELbRmZRnM9vfsopvjo-v8tD-6ODnLh6O-InHK-lIyyWOL47YC5ZwbQjFOjDKpNhmjVBNGUg6aS2CgrU7gLlXaKmstVQklpIt6i9ypd48zE2oxKYIyZSkr42ZBxBlQlpA0gxbd-4M-uJmv2naCAOUUCMZzarCglHcheGPF1BcT6RuBQcw1i7lmsdTcPux-x87uJkYv8R-vLZAtgKeiNM0_cSK_usp_w78AH6WJlA</recordid><startdate>20240422</startdate><enddate>20240422</enddate><creator>Yi, Yaping</creator><creator>Xi, Chanjuan</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9602-7309</orcidid></search><sort><creationdate>20240422</creationdate><title>Organo‐Photoredox Catalyzed C(sp3)−H Bond Arylation of Aliphatic Amides</title><author>Yi, Yaping ; Xi, Chanjuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3285-aa5a62f122694666e34117ece8de9544d353860d6a050dfd70b8cdfcfff4c7433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>aliphatic amide</topic><topic>Aliphatic compounds</topic><topic>Amides</topic><topic>Catalysis</topic><topic>cyanoaromatic compound</topic><topic>C−H bond activation</topic><topic>C−H bond arylation</topic><topic>Hydrogen bonds</topic><topic>Light sources</topic><topic>photocatalysis</topic><topic>Photoredox catalysis</topic><topic>Reagents</topic><topic>Room temperature</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yi, Yaping</creatorcontrib><creatorcontrib>Xi, Chanjuan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yi, Yaping</au><au>Xi, Chanjuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Organo‐Photoredox Catalyzed C(sp3)−H Bond Arylation of Aliphatic Amides</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2024-04-22</date><risdate>2024</risdate><volume>17</volume><issue>8</issue><spage>e202301585</spage><epage>n/a</epage><pages>e202301585-n/a</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>A C(sp3)−H bond arylation of aliphatic amides has been achieved via organophotoredox catalysis. The reaction could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and a range of aliphatic amides is employed as both substrate and solvent in the reaction. This photocatalyzed transformation provides a convenient protocol to afford a board range of N‐benzyl amides.
A C(sp3)−H bond arylation of aliphatic amides with cyanoaromatics has been achieved via photoredox catalysis, which could be realized at room temperature with visible light source and metal‐free catalyst. Quinuclidine is employed as an efficient HAT reagent and aliphatic amide is employed as both reagent and solvent. This photocatalyzed transformation provides a convenient protocol to afford a board range of N‐benzyl amides.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>38126961</pmid><doi>10.1002/cssc.202301585</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-9602-7309</orcidid></addata></record> |
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| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | aliphatic amide Aliphatic compounds Amides Catalysis cyanoaromatic compound C−H bond activation C−H bond arylation Hydrogen bonds Light sources photocatalysis Photoredox catalysis Reagents Room temperature Substrates |
| title | Organo‐Photoredox Catalyzed C(sp3)−H Bond Arylation of Aliphatic Amides |
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