High-efficiency activated phosphorus-doped Ni2S3/Co3S4/ZnS nanowire/nanosheet arrays for energy storage of supercapacitors

(a) Synthesis process of P-Ni2S3/Co3S4/ZnS material; (b) GCD curves of P-Ni2S3/Co3S4/ZnS; (c) Energy density and power density plots of device. [Display omitted] •The introduction of P into multimetal sulfides may enhance the electrochemical activity and optimize the microstructure, thus providing fast charge transfer and improving ion transport kinetics for transition metal sulfides.•The material has a one-dimensional nanowire/two-dimensional nanosheet-like coexisting microscopic morphology, which facilitates the exposure of abundant active centres and promotes the transport and migration of ions in the electrolyte,•The prepared P-Ni2S3/Co3S4/ZnS has a specific capacity of 1358 C g−1 at 1 A/g, and the assembled P-Ni2S3/Co3S4/ZnS //AC device with an energy density of 48.8 Wh kg−1 and excellent cycling performance. Transition metal sulfides (TMS) have been considered as a promising group of electrode materials for supercapacitors as a result of their strong redox activity, but high volumetric strain of the materials during electrochemical reactions causes rapid structural collapse and severe capacity loss. Herein, we have synthesized phosphorus-doped (P-doped) Ni2S3/Co3S4/ZnS battery-type nanowire/nanosheet arrays as an advanced cathode for supercapacitor through a two-step process of hydrothermal and annealing treatments. The material has a one-dimensional nanowire/two-dimensional nanosheet-like coexisting microscopic morphology, which facilitates the exposure of abundant active centers and promotes the transport and migration of ions in the electrolyte, while the doping of P significantly enhances the conductivity of the electrode material. Simultaneously, the element phosphorus with similar atomic radii and electronegativity to sulfur may act as electron donors to regulate the electron distribution, thus providing more effective electrochemically active sites. In gratitude to the synergistic effect of microstructure optimization and electronic structure regulation induced by the doing of P, the P-Ni2S3/Co3S4/ZnS nanoarrays provide a superior capacity of 2716 F g−1 at 1 A/g, while the assembled P-Ni2S3/Co3S4/ZnS//AC asymmetric supercapacitor exhibits a high energy density of 48.2 Wh kg−1 at a power density of 800 W kg−1 with the capacity retention of 89 % after 9000 cycles. This work reveals a possible method for developing high-performance transition metal sulfide-based battery-like electrode materials for supercapacitors through microstructure optimizat