Nickel-catalyzed regioselective hydrogen isotope exchange accelerated by 2-pyridones
A nickel-catalyzed hydrogen isotope exchange has been developed with acetone- as the deuterium source. The reaction showed an improved kinetic feature of H/D exchange under the assistance of 2-pyridones, efficiently affording regioselective labeled aryl and alkyl carboxamides.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-01, Vol.60 (4), p.384-387 |
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| container_issue | 4 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 60 |
| creator | Jiang, Zhi-Jiang Xu, Si-Han Su, Yuhang Hu, Erxun Han, Jiawei Bai, Jian-Fei Tang, Bencan Chen, Jia Gao, Zhanghua |
| description | A nickel-catalyzed hydrogen isotope exchange has been developed with acetone-
as the deuterium source. The reaction showed an improved kinetic feature of H/D exchange under the assistance of 2-pyridones, efficiently affording regioselective labeled aryl and alkyl carboxamides. |
| doi_str_mv | 10.1039/d3cc05257e |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-01, Vol.60 (4), p.384-387 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2902965038 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Deuterium Exchanging Hydrogen isotopes Nickel Regioselectivity |
| title | Nickel-catalyzed regioselective hydrogen isotope exchange accelerated by 2-pyridones |
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