An urban metabolism framework purpose to assess the dynamics of linear alkylbenzenes (LABs) discharge flows and driving forces at the city level in Guangdong province, China

Linear alkylbenzenes (LABs) are a class of molecular markers derived from anthropogenic activities. A comprehensive understanding of the mechanism that determines their entry into anthroposphere, in terms of magnitude and pathway, is the prerequisite to establish effective mitigation measures. This study develops a methodology framework to analyze the source-sink interactions and driving factors of the direct and indirect LAB discharges from production and living activities in Guangdong Province, China from 2004 to 2017. Results indicated that the total LAB discharges of Guangdong into the environment were averaged at 2.9 kt yr−1, of which 61.9% originated from the Pearl River Delta (PRD) urban agglomeration. An average proportion of 76.0% was discharged into water bodies with the remaining released into land bodied. From 2014 to 2017, the LAB discharges increased by seven times, resulting from the steady increase of urban residential sources, while contribution from industrial sources continuously declined during the studied period. Meanwhile, the discharging hotspots expanded from Guangzhou city to other super-cities around it, including Shenzhen and Dongguan. The other cities exhibited a decreasing trend in discharges as a function of distance from these hotspot cities. The multisectoral sources of LABs differed considerably among cities, and the source contribution of each city changed significantly with progressive urbanization. The factor decomposition analysis indicated that LAB discharges in PRD cities primarily contributed by the pollutant concentration and reflected the treatment structure, while peripheral cities of the PRD mainly contributed by the per capita consumption and pollutant discharge per unit of GDP. Overall, our results provide a scientific database and supports for the regional co-remediation of anthropogenic pollution. [Display omitted] •A methodology framework to apportion LABs from production and living activities was developed.•LAB discharges of Guangdong increased by seven times primarily due to intensive residential activities.•LAB discharges were primarily contributed by pollutant concentration and treatment structure.•Individual cities significantly differed in discharging amounts, sectors, and driving factors.